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High energy chemistry journal archive of numbers. What she studies: High energy chemistry. Agreement - public offer

Specialty code: 02.00.09 High Energy Chemistry

Description of the specialty: High-energy chemistry is a branch of chemical science that studies chemical reactions and transformations that occur in matter under the influence of non-thermal energy. The mechanisms and kinetics of such reactions and transformations are characterized by substantially nonequilibrium concentrations of fast, excited or ionized particles with an energy higher than the energy of their thermal motion and, in some cases, chemical bonding. The carriers of nonthermal energy acting on matter are accelerated electrons and ions, fast and slow neutrons, alpha and beta particles, positrons, muons, pions, atoms and molecules at supersonic speeds, quanta of electromagnetic radiation, as well as pulsed electric, magnetic and acoustic fields. The processes of high-energy chemistry are distinguished by their temporal stages into a physical one, which occurs in femtoseconds or less, during which non-thermal energy is distributed unevenly in the medium and a "hot spot" is formed, a physicochemical one, during which non-equilibrium and inhomogeneity in a spot "and, finally, chemical, in which the transformations of matter obey the laws of general chemistry. The variety of types of carriers of nonthermal energy causes the introduction of a number of independent areas of chemical science into the range of high energy chemistry, including laser chemistry, plasma chemistry, radiation chemistry, photochemistry, mechanochemistry, and nuclear chemistry. In studies of high-energy chemistry, in addition to instrumental methods for recording fast chemical and physical processes, electronic and optical spectroscopy, mass spectrometry, resonance spectrometry, positron annihilation, methods of quantum electronics, atomic and nuclear physics, theoretical chemistry, in particular, mathematical and quantum chemistry, as well as methods of physical and analytical chemistry.

Field of study:
1. Establishing the laws governing the interaction of carriers of nonthermal energy with matter in any state of aggregation.
2. Determination of the characteristic parameters and local distribution of nonthermal energy in the "hot spot" at different types interaction of this energy with matter.
3. Identification, qualitative and quantitative of the primary products of chemical reactions in the "hot spot", their reactivity and other physical and chemical properties; study of the composition of intermediate particles and end products of chemical reactions, as well as the mechanisms and kinetics of these reactions.
4. Study of photochemical reactions, ionomolecular reactions, reactions involving solvated electrons and free radicals.
5. Determination of the resistance of compounds and materials to the effects of certain carriers of non-thermal energy.
6. Application of high-energy chemistry processes in chemical synthesis, aimed at modifying the properties of materials, surface treatment and coating, methods of cleaning and processing industrial waste and other applied problems of chemistry.
7. Development, creation and optimization of technologies using high-energy chemistry processes.

Branch of Sciences:
Technical science
chemical sciences
physical and mathematical sciences

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2.2. Works (Content) - electronic versions of scientific publications, including periodicals, as well as non-periodical publications presented in electronic form on the Internet in various formats, posted on the Website of the Electronic Library System, available to Users through the Website of the Electronic Library System.

2.3. Catalog is a collection of Works.

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5.4. The price of enabling the User, an individual, to view, read and download the Works is indicated on the Website of the "Electronic Library System" in the relevant sections. To users who are legal entities, prices are sent by the "Site Administration" upon request via the agreed communication channels. The "Site Administration" has the right to unilaterally change the current prices by posting relevant information on the Site of the "Electronic Library System" or informing Users in another accessible way. Any price change does not apply to already paid access.

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6.1. The user assumes full responsibility and risks associated with the use of the Catalog.

6.2. The user is fully responsible for the use of the Login and Password by third parties.

6.3. The User is fully responsible for the use by third parties of the information transmitted by the "Site Administration" to the email address specified by the User during registration.

6.4. The "Site Administration" is not responsible for any expenses of the User or direct or indirect damage that may be caused to the User as a result of using the Catalog.

6.5. The "Site Administration" is not responsible for the quality of access to the Catalog via the Internet.

6.6. Under no circumstances is the "Site Administration" responsible for the use of the Login and Password by third parties.

6.7. The "Site Administration" is not responsible for direct or indirect damage incurred by the User as a result of data transmission errors, failures / defects in the operation of software and / or equipment, data loss and damage, data processing or display errors, delays in data transmission and others failures that occurred through no fault of the "Site Administration".

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6.10. Under no circumstances is the "Site Administration" responsible for any expenses of the User or direct or indirect damage, including lost profits or lost data, damage to honor, dignity or business reputation that may be caused to the User as a result of using the Site and (or) related services ...

6.11. If it is impossible for the "Electronic Library System" to provide the User with the ability to view, read and download the Works for reasons beyond the control of the "Site Administration", the "Site Administration", upon the User's request, refunds the received advance payment. In this case, the amount of responsibility of the "Site Administration" is limited to the amount of the advance payment received from the User for the ability to view, read and download the Work, which was not provided.

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9.3. The "Site Administration" has the right to amend the Agreement with the obligatory posting of the relevant information on the Site of the "Electronic Library System" no later than 30 (thirty) calendar days prior to the entry into force of the relevant changes.

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10.2. If the Parties do not come to an agreement, these disputes and disagreements are resolved in court in accordance with the current legislation of the Russian Federation in the court at the location of FSUE Publishing House Nauka in accordance with the rules of jurisdiction and jurisdiction.

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11.1. The User's consent to the provision of personal information is determined by agreement with this public offer, which occurs automatically when the User goes through the registration procedure on the Site.

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11.3. The "Site Administration" collects and stores only the User's data necessary for the functioning of the Site. The "Site Administration" may use the User's data to identify him, clarify payment data, provide personalized services, provide feedback to the User, process applications and requests, perform impersonal statistical calculations and improve the quality of services provided to the User.

The journal publishes original and review articles, brief reports, letters to the editor on molecular and supramolecular photochemistry, radiation chemistry, plasma chemistry, chemistry of new atoms, processes and materials for optical information systems, on the scientific basis of the relevant technologies, as well as the chronicle and book reviews in the field of high energy chemistry.

From the second half of 2007, the journal will publish materials on the topics of scientific and applied photography. Earlier (until 2003) "The Journal of Scientific and Applied Photography" was published as an independent publication.

Archive of scientific articles from the magazine "Chemistry of High Energies"

  • J-Aggregation of Thiacarbocyanine Dye in Reverse Microemulsions

    S.B. BRICHKIN, A. V. IVANCHIKHINA, A. V. Nevidimov - 2015

    The J-aggregation of thiacarbocyanine dye pyridinium salt of 3,3-di - (- sulfopropyl) -4,5,4,5-dibenzo-9-ethylthiacarbocyanine betaine (DEC) in reverse microemulsions of bis- (2-ethylhexyl) sodium sulfosuccinate (AOT ) / n-hexane / water and polyoxyethylene (5) nonylphenyl ether (NP5) / cyclohexane / water. In such systems, the dye is present mainly in the form of a trans monomer and J-aggregate. It has been shown that the equilibrium between these forms is determined by the solubility of the trans monomer in monolayers of surfactant molecules covering the microemulsion droplets. When the total concentration of the dye in the microemulsion is less than the solubility, the equilibrium state corresponds to the presence of the dye only in the trans-monomer form. When the concentration exceeds the solubility, the excess dye forms J-aggregates, which gradually enlarge and precipitate. For reverse microemulsions AOT / n-hexane / water, the found solubility was / = (1.45 ± 0.34) 10-5.

  • LASER PLASMA INTERACTION DURING VISIBLE AND IR LASER ABLATION OF CHROMITE MINERAL TARGET

    HANIF M., SALIK M., WANG J., ZHANG X.Q. - 2015

    In this work, we present optical emission studies of the laser induced Chromite mineral plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched pulsed Nd: YAG laser. The spectra predominantly reveal the spectral lines of neutral Cr as well as dominant spectral lines of constituent elements. The experimentally observed line profiles of neutral chromium have been used to extract the electron temperature (Te) using Boltzmann plot method. Whereas, the electron number density (Ne) has been determined from the Stark broadened line profiles. We have also studied the variation of electron temperature and electron number density as a function of laser irradiance at atmospheric pressure. We have also studied the variation of these plasma parameters (Te and Ne) as a function of the laser irradiance as well as distance along the direction of plasma plume. The validity of the assumption of local thermodynamic equilibrium (LTE) is also discussed in the light of the experimental data and analysis.

  • PREPARATION OF COLLOIDAL LEAD SULFIDE NANOPARTICLES BY LASER ABLATION IN WATER FOR OPTOELECTRONIC DEVICES APPLICATIONS

    ISMAIL RAID A. - 2015

    In present work, lead sulfide PbS nanoparticles NPs are synthesized by laser ablation of lead sulfide target in double distilled water using 0.532 and 1.064 wavelengths. The transmission electron microscopy TEM, atomic force microscopy AFM and X-ray diffraction XRD were used so as to determine the shape, size, distribution, and structure of the nanoparticles prepared with different laser wavelengths. X-ray diffraction results confirmed that the lead sulfide nanoparticles crystallized in the cubic phase and presents a preferential orientation along (200) plane and with no observation of any incomplete phases. Optical band gap values ​​of 1.9 and 2eV for the lead sulfide nanoparticles were determined by UV-Vis absorption measurements. It was found that the morphology and size of PbS NPs depend on laser wavelength. To check the possibility of synthesized nanoparticles for optoelectronic devices, a novel type of solution-processed heterojunction photodetector, prepared by drop cast film of colloidal lead sulfide nanoparticles NPs onto n-type single crystal silicon wafer was demonstrated. The effect of laser wavelength on the electrical characteristics and photosensitivity of p-PbS / n-Si heterojunction has been investigated.

  • THERMOLUMINESCENCE RESPONSE OF MULTIMODE FLUORINE-DOPED SIO2 OPTICAL FIBERS AND TLD 100 WITH 6 MEGA VOLT PHOTON IRRADIATION

    HOSSAIN I., MUBARAK A.A., NURSYAZWANIE R., SAEED M.A., WAGIRAN H. - 2015

    This study investigates and compares the results of thermoluminescence responses, its linearity, sensitivity with various dose ranges and TL glow curve of Fluorine-doped silica fiber and TLD-100 materials. The TL responses of the Fl-doped silica fibers and TLD 100 were kept in gelatin capsule and irradiated with 6-MV photon at the dose range from 0.5 Gy to 4.0 Gy. Siemens model Primus 3368 linear accelerator located at Hospital Sultan Ismail; Johor Bahru has been used to deliver the photon beam to the samples. The TL-signal of TLD 100 media exhibits a significant linear dose to signal relationship with an increase in doses. The sensitivity of Fl-doped optical fiber is negligible to TLD 100 media.

  • THERMOLUMINESCENCE RESPONSE OF YTTERBIUM-DOPED SILICON DIOXIDE FIBER

    ABDUL PATTAH N.F., HOSSAIN I., SAEED M.A., WAGIRAN H. - 2015

    In this study, thermoluminescence properties of Yb-doped of SiO2 optical fiber such as linearity, sensitivity and dose response have been studied. Samples were placed in the gelatin capsules to irradiate with photons from Cobalt-60 of the dose range between 10–100 Gy. The beams were provided by Gammacell 220, available at Universiti Kebangsaan Malaysia, Bangi, Malaysia. The glow curves were analyzed to determine various characteristics of the thermoluminescence. The TL response as a function of dose is linear up to 40 Gy. The sensitivity of Yb-doped optical fiber is 0.136 nC mg-1 Gy-1.

  • TIME FUNCTION TRIPLE LANGMUIR PROBE MEASUREMENTS IN LOW FREQUENCY PULSED DC DISCHARGE PLASMA

    ALI A., FAROOQ M.U., GHAFFAR CH. A., KHAN Y., NAZ M.Y., QAYYUM A., SHUKRULLAH S. - 2015

    This study investigated the temporal profiles of electron temperature and number density in rectified DC air discharge generated with a 50 Hz step-up transformer. An in-house built triple Langmuir probe and circuitry were used to diagnose the plasma parameters as a function of input voltage and filling gas pressure. A tungsten metal wire capable of withstanding the high temperatures was used as probe tip material. The temporal profiles revealed an increase in electron temperature with input voltage in the range of 380 to 450 V, whereas, an inverse relation between number density and input voltage was evident in the given work. The observed trend in the plasma parameters was absolutely reversed in case of the filling gas pressure. The electron temperature linearly decreased with an increase in pressure from 1 to 4 mbar, whereas a linear increase in number density with pressure was seen in the temporal profiles. Finally, it was concluded that the results for the tested plasma parameters were consistent and the in-house built probe functioned well in DC discharge for the used range of voltage and filling pressure.

  • INTERACTION OF TRIPTOFAN AND ITS DERIVATIVES WITH OXYGEN- AND NITROCENTRATED RADICALS

    S. D. Brinkevich, R. L. SVerdlov - 2015

    The interaction of tryptophan and its derivatives with nitrogen-centered radicals of 2,2-diphenyl-1-picrylhydrazyl and oxygen-centered radicals formed during the radiolysis of oxygenated ethanol and its aqueous solutions was studied. It was found that tryptophan, 5-hydroxytryptophan, serotonin, harman, harmine and harmaline, in contrast to pyrrole, indole and melatonin, are able to reduce oxygen-centered radicals due to the reaction of electron transfer from the lone pair of nitrogen atoms. It was shown that serotonin and 5-hydroxytryptophan reduce 2,2-diphenyl-1-picrylhydrazyl radicals due to the transfer of a hydrogen atom from the hydroxyl groups of molecules. At the same time, pyrrole, indole, tryptophan, melatonin, harman, harmine and harmaline, which do not contain a phenolic hydroxyl group in their structure, do not interact with 2,2-diphenyl-1-picrylhydrazyl radicals. The final molecular products of the interaction of serotonin and 5-hydroxytryptophan with 2,2-diphenyl-1-picrylhydrazyl radicals were identified by gas chromatography-mass spectrometry.

  • INTERCONNECTION OF ADHESION, CONTACT AND ELECTRIC PROPERTIES OF POLYTETRAFLUOROETHYLENE FILMS MODIFIED IN A DC DISCHARGE

    A. B. Gil'man, A. S. Kechek'yan, A. A. Kuznetsov, M. S. Piskarev, M. Yu. - 2015

    The relationship between the values ​​of the contact angle, peeling resistance, and effective density of the surface charge of polytetrafluoroethylene films modified in a DC discharge at the anode and cathode has been investigated. It is shown that there is a correlation between the adhesive characteristics of the film treated in a DC discharge, a change in the contact angle, and the value of the effective surface charge.

  • VIBRONIC STRUCTURE OF ELECTRONIC ABSORPTION AND FLUORESCENCE SPECTRA OF PYRENE IN A COMPLEX WITH BETA-CYCLODEXTRIN IN THE PRESENCE OF NON-POLAR AND POLAR SOLVENTS

    V. G. Avakyan, M. V. Alfimov, A. V. Koshkin, and V. B. Nazarov - 2015

    The possibility of using pyrene (Py) as a fluorescent probe (FZ) in cyclodextrin – pyrene – analyte complexes for analytes (A) of different polarity in aqueous solutions has been investigated. In the UV-VIS spectrum of an aqueous solution of Py in the presence of CD, bands were found for the first time, proving the formation of a complex [email protected] CD. The characteristic of the FZ is the I3 / I1 ratio in the fluorescence spectrum, where I3 is the intensity of the third vibronic line at 800 cm – 1, and I1 is the intensity of the 0–0 transition. I3 / I1 value for [email protected] CD is highly sensitive to the addition of a few M / L A to an aqueous solution. Dependences (I3 / I1) / C on the permittivity function A f = (- 1) / 2 + 1) are divided into two straight lines with different slopes for non-polar and polar A. [email protected] CDs calculated by the PM3 quantum chemical method. An increase in (I3 / I1) / C corresponds to the thermodynamically more stable complex 2A [email protected] CD.

  • EFFECT OF ALBUMIN AND WATER-SOLUBLE ANALOGUES OF VITAMINS E, Q, K ON FREE RADICAL FRAGMENTATION OF PHOSPHOLIPIDS

    I. V. MELSITOVA, I. L. YURKOVA - 2015

    The effect of trolox C, ubiquinone Q0, phthicol, and bovine serum albumin (BSA) on free radical fragmentation of dimyristoylphosphatidylglycerol (DMPG) in model membranes exposed to γ-radiation was studied. It was found that ubiquinone Q0 and phthicol are more effective (1.8 1.9 times) compared to trolox C (1.5 times) in reducing the radiation-chemical yield of dimyristoyl phosphatidic acid (DMPA), a molecular product of DMPG fragmentation. BSA has a protective effect on the fragmentation of DMPG in a dose-dependent manner, with a lipid: protein ratio (30: 1), the DMPA yield is halved.

  • EFFECT OF ASCORBIC ACID AND ITS DERIVATIVES ON RADIATION-INDUCED TRANSFORMATIONS OF OXYGENATED ETHANOL AND ITS AQUEOUS SOLUTIONS

    Brinkevich S. D. - 2015

    With -irradiation of ethanol and its aqueous solutions at pH 7 saturated with oxygen, ascorbic acid is capable of reducing the yields due to the reduction of peroxyl radicals, and the main products of radiolysis. In addition to the ability to inhibit radiation-induced transformations of oxygenated ethanol and its aqueous solutions at pH 7, ascorbic acid can enter into reactions leading to the formation of additional reactive oxygen species, which must be taken into account when considering its role in free radical processes in biosystems.

  • EFFECT OF HYPOCHLORITE ON RADIOLYSIS OF AQUEOUS PROPANOL-2

    V.S. KOSOBUTSKY - 2015

    DOI: 10.7868 / S0023119315040105 References

  • INFLUENCE OF LIGHTING INTENSITY ON THE RATE AND SELECTIVITY OF PHOTOSENSITIZED OXIDATION OF DIBUTYL SULFIDE ON FULLERENE C70

    A. V. Arsent'ev, A. V. Vorontsov, and V. N. Parmon - 2015

    Photoinitiated oxidation of dibutyl sulfide (DBS) with atmospheric oxygen in a toluene solution of fullerene C70 under visible light illumination with a wavelength of 500–700 nm leads to the formation of dibutyl sulfone as the main detectable product, as well as dibutyl sulfoxide, dibutyl disulfide, and butanal. A change in the irradiance of the reaction mixture from 2.2 to 44 mW / cm2 insignificantly increases the quantum efficiency of DBL consumption from 4.5 to 5.9%. This increases the selectivity of sulfoxide formation and decreases the selectivity of sulfone formation.

  • INFLUENCE OF THE PARAMETERS OF A DIELECTRIC BARRIER DISCHARGE OF ATMOSPHERIC PRESSURE IN OXYGEN ON THE KINETICS OF SULFONOL DECOMPOSITION IN WATER

    E. S. Bobkova, A. A. Borzova, V. V. Rybkin, A. I. Shishkina - 2015

    The kinetics of the decomposition of sulfonol and the formation of products of its destruction under the action of a dielectric barrier discharge of atmospheric pressure in oxygen on an aqueous solution in the power range of 0.4–4 W. It was shown that the decomposition products in the liquid phase are carboxylic acids, aldehydes, and carbon dioxide in the gas phase. Was the energy efficiency of decomposition determined, which was (4.4–12.7)? 10-3 molecules per 100 eV of input energy. Assumptions are made about the mechanisms of the ongoing processes.

  • INFLUENCE OF THE NATURE OF THE ANION OF CATIONIC POLYMETHINE DYES ON THE PHOTOVOLTAIC PROPERTIES OF POLYMER PHOTOSEMICONDUCTOR COMPOSITES

    G. V. Bulavko - 2015

    It was found that the nature of the anion of cationic polymethine dyes in polymer solar cells affects the photovoltage. Based on the study of the spectral-luminescent properties, it was found that polymethines in them form contact ion pairs. It is shown that the difference in the behavior of anions is determined by their ability to photoinduced electron transfer in these pairs.

  • INFLUENCE OF A HEAVY CENTRAL ATOM ON THE PHOTOELECTRIC, NONLINEAR OPTICAL AND PHOTOREFRACTIVE PROPERTIES OF METALLOPHTHALOCYANINES

    A. V. Vannikov .NS. - 2015

    Measurement of the photoelectric and photorefractive characteristics of 2,3,9,10,16,17,23,24-tetra (15-crown-5) phthalocyaninato-yttrium (III) acetate [(15C5) 4Pc] Y (OAc) a decrease in the quantum yield of the formation of charge carriers 0 and the coefficient of photorefractive two-beam amplification with an increase in the atomic weight of the central metal in the series of related phthalocyaninates of gallium (III), yttrium (III), ruthenium (II), and indium (III). The revealed regularities can be caused by an increase in the spin-orbit interaction constant with an increase in the atomic weight of the central metal, which leads to an increase in both the contribution of triplet-excited associates to the formation of mobile charge carriers and the rate of the reverse reaction T1 S0, which effectively suppresses the formation of charge carriers through triplet-excited state. Measurement of the photoelectric and photorefractive characteristics at 1064 nm showed that in the composite polyvinylcarbazole / supramolecular assemblies of the yttrium complex, the quantum yield of electron - hole pairs is 0 = 0.6 and the double-beam gain of the laser beam is about = 35 cm - 1 at E0 = 120 V / μm. The dielectric susceptibility measured by z-scanning of a solution of the yttrium complex in tetrachloroethane (1 mg in 1 ml) is (3) = 4.2 10-10 esu.

  • GAMMA-RADIOLYSIS OF THE BINARY SYSTEM “ETHANOL-WATER” IN THE PRESENCE OF OXYGEN

    N. V. Marchenko, A. V. Nikitin, and A. B. Sazonov - 2015

    Studies of gamma-radiolysis of the aerated ethanol – water system in a wide range of component concentrations show that the main process in such a system is the selective radiative oxidation of ethanol to acetaldehyde. The by-products that accumulate in the liquid phase are 2,3-butanediol and formaldehyde. The selectivity of the process increases with an increase in the alcohol content and decreases with an increase in the radiation dose. The theoretical model of radiolysis created within the framework of this work gives good quantitative agreement with the experimental data. The calculated curves of accumulation of products have turning points characterized by a sharp change in the radiation-chemical yield. Their occurrence is associated with the complete burnout of oxygen in a closed system or with insufficiently fast oxygen entry into the liquid in the two-phase “liquid-gas” system.

  • HOLOGRAPHIC ENVIRONMENT BASED ON HALOGEN-CONTAINING SOLIGOMER

    P. HETMANCHUK, I. I. DAVIDENKO, N. A. DAVIDENKO, E. V. Mokrinskaya, V. A. Pavlov - 2015

    The information properties of the recording media for the photothermoplastic method of recording holograms with films of oligomeric composites based on carbazolyl-containing co-oligomers, one of which contains Br atoms, have been investigated. A medium based on a Br-containing co-oligomer has a higher holographic sensitivity due to a higher discharge rate of the film surface during exposure and the formation of a latent electrostatic image.

  • STUDY OF THE INFLUENCE OF CHARGE ACCEPTORS ON THE PROCESS OF RADIATION-CHEMICAL CARBOXYLATION OF THE INDOL-SERIN SYSTEM

    L. N. Zhigunova, G. V. Nichipor, and O. V. Shevtsova - 2015

    Considerable interest in the radiation-chemical carboxylation of the indole – serine system is due to the prospect of its use for the production of an essential amino acid, tryptophan. In this work, we study the effect of charge acceptors, biphenyl and hydrogen peroxide, on the kinetics of radiolysis of the system. It was found that the solvated electron plays a decisive role in the mechanism of tryptophan formation.

  • PULSE HEATING OF WATER AT THE SURFACE OF GOLD NANOPARTICLES: FEMTOSECOND LASER SPECTROSCOPY OF THE ENERGY RELAXATION OF A WATER COLLOID OF PLASMON NANOPARTICLES UNDER STRONG EXCITATION

    A. V. Aibush, A. A. Astaf'ev, F. E. Gostev, N. N. Denisov, V. A. Nadtochenko, A. A. Titov, A. M. Shakhov, I. V. Shelaev - 2015

    The dynamics of differential absorption spectra of gold nanoparticles in a wide range of values ​​of the excitation energy density is investigated by the method of femtosecond laser spectroscopy. The position of the peak of the plasmon resonance depends significantly on the dielectric properties the environment, which makes it possible to use plasmonic nanoparticles as an optical probe. This work demonstrates the possibility of using femtosecond laser spectroscopy methods, based on the analysis of differential absorption spectra of gold nanoparticles in an aqueous colloid, to characterize the state of a water nanolayer surrounding a nanoparticle. In particular, at high excitation energy densities in the absorption band of the plasmon resonance, spectral-kinetic features are revealed, which indicate vaporization in the nanolayer around the gold particle.

The concept of high-energy physics is now quite well known, including to the common man, because in recent years many giant projects have been created in this area (first of all, the Large Hadron Collider). High-energy physics at the initial level is understandable to many: everyone knows that there is a search for new elementary particles, new elements are synthesized through collisions, for this giant installations are built, tunnels tens of kilometers long, and even at the everyday level it is clear that this is due to very high energies. Far fewer people know what “high energy chemistry” is, even in a professional chemical environment. Not because it is something exotic, but because this term has not yet found such widespread use. Although, if you understand its deep essence, everything becomes quite obvious.

1. Thermal reactions

If in the Large Hadron Collider we are talking about energies that are created by giant generators, about insane discharges that can kill a person, then in high-energy chemistry everything is different. Sunlight entering through a window in a room is already high energy for the chemical system. It is important to determine which criterion works here.

How do almost all chemical reactions that we know from school start? The vast majority of reactions are due to thermal energy. Thermal energy is imparted to the system, certain vibrational modes are excited, the molecule or parts of the molecule begin to move differently. If you look at it from the point of view of quantum chemistry, then the system gets to a higher vibrational level and there behaves in such a way that the reaction becomes inevitable. There are terms such as “adiabatic” and “non-adiabatic processes” (instead of the second term, one can say “diabatic” so that there is no double negation in a mixture of Russian and Greek), and if thermal reactions are adiabatic, then high-energy chemistry deals precisely with non-adiabatic processes ...

2. Electronically excited state

Thermal reactions are what happens within one potential energy surface. If we imagine a mountain range, then a thermal reaction is a transition from one valley to another valley through a mountain pass. At the same time, most likely, in the second valley, everything is more favorable in energy, roughly speaking (continuing the analogy, we can say that it lies lower). This is not the case with high energy chemistry. Here we are not on one surface, but on some other. This other surface is called the electronically excited state. That is, if we continue the analogy with the mountain pass, we climb the tower, the funicular, and this funicular goes over the mountain pass. Thus, instead of walking across the pass, we sweep over it. How is this expressed in terms of chemical processes? High energies can be communicated, for example, by light, which corresponds to one of the branches of high-energy chemistry - photochemistry. Or ionizing radiation, which corresponds to radiation chemistry. In the overwhelming majority of cases, they are higher than something that can be communicated to the system using heat. At the same time, from the point of view of physics, these are rather low energies, but if we talk about the excitation of a chemical system, that is, how atoms behave in a molecule, there is a very significant difference, and due to the fact that we go to another potential surface energy, a lot of other possibilities open up. Imagine that there is some kind of insurmountable peak, but if you drive over it, you will be able to get to where we would not have reached on foot. Here this analogy is very revealing. The fact that other electronically excited states are involved in the system opens the way to new reaction mechanisms. And this is valid for both photochemistry and radiation chemistry, as well as for the third section of high-energy chemistry - plasma chemistry.

3. Chemistry of high energies in everyday life

If carrying out radiation-chemical reactions requires special equipment, sources of ionizing radiation (these include electron beams, gamma radiation, X-rays), then some of the simplest of photochemical experiments can be carried out even at home. That is, if you put some bright postcard on the window for a couple of days or for a week in the summer, you will see that it fades. This means that a photochemical reaction takes place: the light is absorbed by the dye on the paper, and processes take place that would not have happened if the postcard were simply lying in a warm place, because the light carries enough energy to transfer the system to electronically excited state.

4. Photochemical reactions

Photochemical reactions in a primitive form have been known since medieval times, but the nature of these phenomena became fully understood only in the 20th century. Although in the 19th century some quantitative patterns of photochemical reactions were already described, then scientists could only carry out some simple processes, those that can now be carried out in workshops in physical chemistry, for example, the decomposition of hydrogen peroxide. Photochemistry is a gigantic branch of chemistry that is directly related to macromolecular chemistry, since, for example, many polymers can be obtained under the action of light, and to biochemistry, because all people exist thanks to photochemistry, since photosynthesis is a photochemical process.

5. Three sections of high energy chemistry

The concept of "high energy chemistry" should in no way be confused with the concept of "high energy physics". High-energy chemistry includes three broad divisions: photochemistry, radiation chemistry, and plasma chemistry. Despite the fact that the phrase "radiation chemistry" sounds dangerous, radiation chemistry does not directly deal with radioactivity and radionuclides. Chemists simply shine an X-ray on something, and because of this, some processes take place, and this does not mean at all that radioactivity appears in the object. The most intuitive branch of high energy chemistry is photochemistry, which studies reactions under the influence of light. This section includes the study of photosynthesis and, for example, what can happen under the influence of light in beer (it's not for nothing that it is stored in dark bottles), or what happens when you break a special luminescent stick in a nightclub, and it starts to glow, or the phenomenon due to which film photography exists.

6. Use of high energy chemistry in industry

Processes related to high energy chemistry are already widely used in industry. This is the production of polymers both by photoinitiation and by means of radiation-chemical initiation of polymerization reactions, and radiation-chemical water purification is one of the most environmentally friendly methods of purification, and disinfection of products, and a huge number of processes that are associated with photosensitivity. All this can easily develop further, and the effectiveness of these processes is likely to only increase.

Scientometric indicators

Usage
  • 6795 Full Text Downloads 2018

    Springer measures downloads of full text from the SpringerLink platform according to COUNTER (Counting Online Usage of NeTworked Electronic Resources) standards.

  • 23 Usage Factor 2017/2018

    The Usage Factor is a value calculated according to the rules recommended by COUNTER. This is the average (median) number of downloads in 2017/18. for all articles published online in the same journal during the same period. The utilization factor calculation is based on data conforming to COUNTER standards on the SpringerLink platform.

Influence
  • 0.634 Impact Factor 2018

    Impact Factor published by Clarivate Analytics in Journal Citation Reports. Impact factors refer to the previous year.

  • 0.59 Source Normalized Impact per Paper (SNIP) 2018

    Source Normalized Impact per Paper (SNIP) measures the citation contextual impact of a journal by weighing the citations in each subject group. The contribution of each individual citation is the higher in each specific subject category, the less likely (for reasons of subject content) that such a citation will occur.

  • Q4 Quartile: Physical and Theoretical Chemistry 2018

    A set of journals from one subject category are ranked according to their SJR and divided into 4 groups called quartiles. Q1 (green) combines the journals with the highest scores, Q2 (yellow) the next, Q3 (orange orange) the third highest SJR, Q4 (red) the lowest scores.

  • 0.27 SCImago Journal Rank (SJR) 2018

    The SCImago Journal Rank (SJR) is a measure of the scientific impact of a journal that takes into account the number of citations received by the journal and the ranking of the citing journals.

  • 19 Hirsch Index 2018

SCOPE

High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.

Indexing and summarizing

Chemical Abstracts Service (CAS), Chimica, Current Contents / Physical, Chemical and Earth Sciences, EBSCO Academic Search, EBSCO Advanced Placement Source, EBSCO Discovery Service, EBSCO Engineering Source, EBSCO Environment, EBSCO STM Source, Gale, Gale Academic OneFile, Gale InfoTrac, Google Scholar, INIS Atomindex, INSPEC, Institute of Scientific and Technical Information of China, Japanese Science and Technology Agency (JST), Journal Citation Reports / Science Edition, Naver, OCLC WorldCat Discovery Service, ProQuest Central, ProQuest Materials Science and Engineering Database, ProQuest SciTech Premium Collection, ProQuest Technology Collection, ProQuest-ExLibris Primo, ProQuest-ExLibris Summon, Reaction Citation Index, Reaxys, SCImago, SCOPUS, Science Citation Index, Science Citation Index Expanded (SciSearch), Semantic Scholar.