Analogs of Russian and foreign steels. Duplex stainless steels Stainless steel 1.4301 characteristics
Steel is an alloy of iron with carbon.
Depending on the percentage of carbon " WITH"in such an alloy, steels have different properties and characteristics. By adding various chemical elements to the alloy during smelting (called" alloying elements "), steels with a wide variety of properties can be obtained. Steels with similar characteristics were collected in groups.
In order for the steel to be called stainless, the chromium content in the composition of such steel must be more than 10.5% and at the same time the carbon content is low (no more than 1.2%). The presence of chromium gives the steel its corrosion resistance - hence the name "stainless". In addition to chromium, as an "indispensable stainless component", alloying elements can also be present in the composition of stainless steel: nickel (Ni), molybdenum (Mo), Titanium (Ti), Niobium (Nb), Sulfur (S), Phosphorus (P) and other elements whose combination determines the properties of the steel.
Main grades of stainless steels for fasteners
Historically, the development and smelting of new stainless steels and alloys is closely associated with advanced technology industries: aircraft and rocketry. The leading states in the world in these branches of mechanical engineering were the USSR and the USA, they were in a state of "cold war" for a long time and each went its own way. In Europe, the technological leader in the twentieth century was and is Germany. Each of them developed its own classification of stainless steels: in the USA - the system AISI, in Germany - DIN, in USSR - GOST.
For a very long time, there was no question of any cooperation between these three leaders - hence the large number of today's standards for stainless steels, and their very difficult, and sometimes absent, interchangeability.
The United States and Germany are somehow simpler: after all, there has been mutual trade between these countries for decades technical means and technology, which inevitably led to mutual adaptation, and in the area of stainless steel standards too. The most difficult thing is for the countries of the former USSR, where standards developed in isolation from the rest of the world, and today, for many brands of imported stainless steels there are simply no analogues - or vice versa: there are no imported analogues of Soviet stainless steels.
This whole situation is extremely slowing down and complicates the development of domestic mechanical engineering, which is already "on its knees."
As a result, we have the following world standards for stainless steels:
- DIN- Deutsche Industrie Norm
- RU- European standard EN 10027
- DIN EN- German edition of the European Standard
- ASTM- American Society for Testing and Materials
- AISI- American Iron and Steel Institute
- AFNOR- Association Francaise de Normalization
- GOST- State standard
There are no mass or serial manufacturers of stainless steel fasteners in Ukraine, so we all have to study and adapt to foreign classification and marking of stainless steels and fasteners.
In recent years, Russian standards for stainless fasteners, adopting the terminology and markings from European standards (for example, GOST R ISO 3506-2-2009). In Ukraine, most likely, no changes and innovations are expected in the near future ...
And yet, the stainless steels most used for the production of fasteners have approximate analogues in various classification systems - the main ones are given in the following table of correspondences of stainless steel grades for fasteners:
Stainless Steel Standards | Alloying elements content,% | |||||||||
* | DIN | AISI | GOST | C | Mn | Si | Cr | Ni | Mo | Ti |
C1 | 1.4021 | 420 | 20X13 | 0,20 | 1,5 | 1,0 | 12-14 | |||
F1 | 1.4016 | 430 | 12X17 | 0,08 | 1,0 | 1,0 | 16-18 | |||
A1 | 1.4305 | 303 | 12Х18Н10Е | 0,12 | 6,5 | 1,0 | 16-19 | 5-10 | 0,7 | |
A2 | 1.4301 | 304 | 12X18H10 | 0,07 | 2,0 | 0,75 | 18-19 | 8-10 | ||
1.4948 | 304H | 08X18H10 | 0,08 | 2,0 | 0,75 | 18-20 | 8-10,5 | |||
1.4306 | 304L | 03X18H11 | 0,03 | 2,0 | 1,0 | 18-20 | 10-12 | |||
A3 | 1.4541 | 321 | 08X18H10T | 0,08 | 2,0 | 1,0 | 17-19 | 9-12 | 5xS-0.7 | |
A4 | 1.4401 | 316 | 03Х17Н14М2 | 0,08 | 2,0 | 1,0 | 16-18 | 10-14 | 2-2,5 | |
1.4435 | 316S | 03Х17Н14М3 | 0,08 | 2,0 | 1,0 | 16-18 | 12-14 | 2,5-3 | ||
1.4404 | 316L | 03Х17Н14М3 | 0,03 | 2,0 | 1,0 | 17-19 | 10-14 | 2-3 | ||
A5 | 1.4571 | 316Ti | 08Х17Н13М2Т | 0,08 | 2,0 | 0,75 | 16-18 | 11-12,5 | 2-3 | 5xS-0.8 |
In turn, depending on the composition and properties, stainless steels are divided into several subgroups, indicated in the first column:
* - designation of subgroups of stainless steels:
- A1, A2, A3, A4, A5- Austenitic stainless steels - in general, non-magnetic or weakly magnetic steels with a main constituent of 15-20% chromium and 5-15% nickel, which increases corrosion resistance. They can be cold formed, heat treated and welded well. Indicated by an initial letter " A"It is the austenitic group of stainless steels that is most widely used in industry and in the manufacture of fasteners.
- C1- Martensitic stainless steels are significantly harder than austetitic steels and can be magnetic. They are hardened by quenching and tempering, like simple carbon steels, and are mainly used in the manufacture of cutlery, cutting tools and general engineering. More susceptible to corrosion. Indicated by an initial letter " WITH"
- F1- Ferritic stainless steels are much softer than martensitic ones due to their low carbon content. They are also magnetic. Indicated by an initial letter " F"
Austenitic stainless steels of subgroups A2, A4 and others
Marking system for austenitic stainless steels with the letter " BUT"developed in Germany for simplified marking of fasteners. Let us examine in more detail austenitic steels by subgroups:
Subgroup A1
Steel subgroups A1 are characterized by a high sulfur content and, therefore, are most susceptible to corrosion. Become A1 have high hardness and wear resistance.
They are used in the manufacture of spring washers, pins, some types of cotter pins, as well as for parts of movable joints.
Subgroup A2
The most common subgroup of stainless steels in the production of fasteners A2... These are non-toxic, non-magnetic, non-hardenable, corrosion-resistant steels. Easily weldable without becoming brittle. Initially, steels of this subgroup are non-magnetic, but they can exhibit magnetic properties as a result of cold machining - forging, upsetting. They have good resistance to corrosion in the atmosphere and in clean water.
Fasteners and steel products A2 not recommended for use in acids and chlorine-containing environments (e.g. swimming pools and salt water).
Steel fasteners A2 maintains performance up to temperatures of - 200˚C.
In the German classification DIN, A2
- DIN 1.4301 ( American counterpart AISI 304, Soviet closest analogue 12X18H10),
- DIN 1.4948 ( American counterpart AISI 304H, Soviet closest analogue 08X18H10),
- DIN 1.4306 ( American counterpart AISI 304L, Soviet closest analogue 03X18H11).
Therefore, if you see a marking on a bolt, screw or nut A2, it is most likely that this fastener is made of one of these three steels. It is usually difficult to determine more precisely due to the fact that the manufacturer indicates only the marking A2.
All three steels included in the subgroup A2 do not contain Titanium ( Ti) - this is due to the fact that steel A2, mainly, products are produced by stamping, and the addition of titanium to the stainless steel composition significantly reduces the ductility of such steel, and, therefore, such steel with titanium is very difficult to stamp.
Noteworthy are the numbers 18 and 10 in the Soviet designation. 12X18H10 analogue of steel DIN 1.4301... On imported stainless steel dishes, the designation 18/10 is often found - this is nothing more than an abbreviation for stainless steel with a percentage of 18% chromium and 10% nickel - i.e. DIN 1.4301.
Become A2 are often used for the manufacture of dishes and elements of food equipment - therefore the popular name of such steels is closely related to the field of application of steels A2- "food grade stainless steel". Some semantic confusion arose here. The name "food grade stainless steel" is associated with the field of application, not with the properties of steel A2, and this is not quite the correct name, since it is titanium itself that has antibacterial properties - and only stainless steel containing titanium in its composition can rightfully be called "food grade".
Fasteners made of stainless steel subgroup A2 may have some magnetic properties in strong magnetic fields. By themselves have become subgroups A2 non-magnetic, some magnetism appears in bolts, screws, washers and nuts as a result of stresses arising from cold deformation - stamping.
A manufacturing plant, both utensils and fasteners, can use the above-mentioned stainless steels additionally alloyed in very small quantities with some other elements, for example, Molybdenum, to give their products special consumer properties. You can only find out about this with the help spectral analysis in the laboratory - the manufacturer himself may consider the composition of the steel a "trade secret" and indicates, for example, only A2.
Subgroup A3
Steel subgroups A3 have similar properties to steels A2, but at the same time additionally alloyed with titanium, niobium or tantalum. This increases the corrosion resistance of steels at high temperatures and imparts spring properties.
They are used in the manufacture of parts with high rigidity and spring properties (washers, rings, etc.)
Subgroup A4
The second most common subgroup of stainless steels for fasteners is the subgroup A4... Become A4 their properties are also similar to A2 steels, but additionally alloyed with the addition of 2-3% Molybdenum. Molybdenum gives steels A4 significantly higher corrosion resistance in aggressive environments and acids.
Steel fasteners and rigging A4 They are highly resistant to chlorine-containing media and salt water and are therefore recommended for use in shipbuilding.
Steel fasteners A4 maintains performance up to temperatures - 60˚C.
In the German classification DIN, based on the table, such steel A4 can match one of three stainless steels:
- DIN 1.4401 ( American counterpart AISI 316, Soviet closest analogue 03Х17Н14М2)
- DIN 1.4404 ( American counterpart AISI 316L, Soviet closest analogue 03Х17Н14М3)
- DIN 1.4435 ( American counterpart AISI 316S, Soviet closest analogue 03Х17Н14М3)
Since the subgroup A4 has increased corrosion resistance not only in the atmosphere or water, but also in aggressive environments - therefore, the popular name for steel A4"acid-resistant" or also called "molybdenum" because of the content of molybdenum in the steel.
Subgroup stainless steels A4 practically do not have magnetic properties.
Resistance to external conditions different environments for stainless fasteners is given in the article " "
Subgroup A5
Steel subgroup A5 has properties similar to those of steels A4 and with steels A3, since it is also additionally alloyed with titanium, niobium or tantalum, but with a different percentage of alloying additions. These features give steel A5 increased resistance to high temperatures.
Steel A5 as well as A3, has spring properties and is used for the manufacture of various fasteners with high rigidity and spring properties. At the same time, the performance of steel fasteners A5 persists at high temperatures and in aggressive environments.
Applicability of stainless steels for the manufacture of fasteners
Here is a short table of the most common types of fasteners and corresponding to these types of stainless steels:
Fastener name | Subgroup of steels | DIN | AISI |
A2, A4 | |||
A2, A4 | 1.4301, 1.4306, 1.4948, 1.4401, 1.4404, 1.4435 | 304, 304H, 304L, 316, 316L, 316S | |
A2, A4 | 1.4301, 1.4306, 1.4948, 1.4401, 1.4404, 1.4435 | 304, 304H, 304L, 316, 316L, 316S | |
, | 1.4122, 1.4310 | 440A, 301 | |
1.4122, 1.4310 | 440A, 301 | ||
1.4122, 1.4310 | 440A, 301 | ||
A2, A4 | 1.4301, 1.4306, 1.4948, 1.4401, 1.4404, 1.4435 | 304, 304H, 304L, 316, 316L, 316S | |
A2, A4 | 1.4301, 1.4306, 1.4948, 1.4401, 1.4404, 1.4435 | 304, 304H, 304L, 316, 316L, 316S | |
A1, A5 | 1.4305, 1.4570, 1.4845 | 303, 316Ti, 310S | |
1.4122, 1.4310 | 440A, 301 | ||
A1, A2 | 1.4301, 1.4306, 1.4948 | 303, 304, 304H, 304L |
Also, the listed types of fasteners can be made by manufacturers from other grades of stainless steels other than those listed in the table with minor additional "secret" alloying additions to impart specific properties to the steel. For example, retaining rings can be made from such a "special" subgroup stainless steel A2, which is a trade secret of the manufacturer.
Most common stainless steels
Below is a more complete table of the most common types of stainless steels and their correspondence different classifications standards.
Designations of chemical elements in the table: |
Duplex stainless steels are becoming more common. They are made by all major stainless steel manufacturers - and that's why whole line reasons:
- High strength to reduce product weight
- High corrosion resistance, especially stress corrosion cracking
Duplex steels conferences are held every 2-3 years, featuring dozens of in-depth technical articles. Goes active promotion of this type of steel on the market. New grades of these steels are constantly appearing.
But despite all this interest, the share of duplex steels in the world market is, according to the most optimistic estimates, from 1 to 3%. The purpose of this article is to in simple words explain the features of this type of steel. Both advantages and disadvantages will be described duplex stainless steel products.
Overview of Duplex Stainless Steels
The idea for duplex stainless steels originated in the 1920s, and the first melting took place in 1930 in Avesta, Sweden. However, only the last 30 years have seen a noticeable increase in the use of duplex steels. This is explained mainly by the improvement of steel production technology, especially the processes for regulating the nitrogen content in steel.
Traditional austenitic steels such as AISI 304 (analogs to DIN 1.4301 and 08X18H10) and ferritic steels such as AISI 430 (analogs to DIN 1.4016 and 12X17) are fairly easy to manufacture and easy to process. As their names suggest, they consist primarily of one phase: austenite or ferrite. Although these types have a wide range of applications, both of these types have their own technical disadvantages:
In austenitic ones - low strength (conditional yield point 0.2% in the state after austenitizing 200 MPa), low resistance to stress corrosion cracking
Ferritic ones have low strength (slightly higher than that of austenitic ones: the conventional yield point of 0.2% is 250 MPa), poor weldability at large thicknesses, low-temperature brittleness
In addition, the high nickel content in austenitic steels leads to higher prices, which is undesirable for most end users.
The main idea behind duplex steels is to select a chemical composition that produces approximately the same amount of ferrite and austenite. This phase composition provides the following advantages:
1) High strength - the range of the nominal yield strength of 0.2% for modern duplex steel grades is 400-450 MPa. This allows you to reduce the cross section of the elements, and hence their mass.
This advantage is especially important in the following areas:
- Pressure vessels and tanks
- Building structures such as bridges
2) Good weldability of large thicknesses - not as simple as with austenitic, but much better than with ferritic ones.
3) Good toughness - much better than ferritic steels, especially at low temperatures: usually up to minus 50 degrees Celsius, in some cases up to minus 80 degrees Celsius.
4) Resistance to corrosion cracking (SCC) - traditional austenitic steels are particularly prone to this type corrosion. This advantage is especially important in the manufacture of structures such as:
- Hot water tanks
- Brewing tanks
- Concentrating plants
- Pool frames
How the balance of austenite / ferrite is achieved
To understand how duplex steel is obtained, you can first compare the composition of two well-known steels: austenitic - AISI 304 (analogues of DIN 1.4301 and 08X18H10) and ferritic - AISI 430 (analogues of DIN 1.4016 and 12X17).
Structure |
Brand |
EN designation |
|||||||||
Ferritic |
16,0-18,0 |
||||||||||
Austenitic |
17,5-19,5 |
8,0-10,5 |
The main elements of stainless steels can be divided into ferritizing and austenitizing. Each of the elements contributes to the formation of a particular structure.
Ferritizing elements are Cr (chromium), Si (silicon), Mo (molybdenum), W (tungsten), Ti (titanium), Nb (niobium)
Austenitizing elements are C (carbon), Ni (nickel), Mn (manganese), N (nitrogen), Cu (copper)
Ferritizing elements predominate in AISI 430 steel, therefore its structure is ferritic. Steel AISI 304 has an austenitic structure mainly due to its content of about 8% nickel. To obtain a duplex structure with a content of each phase of about 50%, a balance of austenitizing and ferritizing elements is required. This is the reason why the nickel content of duplex steels is generally lower than that of austenitic steels.
Below is a typical composition of duplex stainless steel:
Brand |
EN / UNS number |
Approximate content |
|||||||
LDX 2101 |
1.4162/
|
Low alloyed |
|||||||
1.4062 / S32202 |
Low alloyed |
||||||||
1.4482/
|
Low alloyed |
||||||||
1.4362/
|
Low alloyed |
||||||||
1.4462/
|
Standard |
||||||||
1.4410/
|
Super |
||||||||
Zeron 100 |
1.4501/
|
Super |
|||||||
Ferrinox255/
|
1.4507/
|
Super |
Some of the newly developed grades use a combination of nitrogen and manganese to significantly reduce nickel content. This has a positive effect on price stability.
Currently, the technology for the production of duplex steels is still developing. Therefore, each manufacturer promotes own brand... By all accounts, there are too many grades of duplex steel now. But apparently, we will observe such a situation until the "winners" emerge among them.
Corrosion resistance of duplex steels
Due to the variety of duplex steels, when determining corrosion resistance, they are usually listed together with austenitic and ferritic steels. There is no single measure of corrosion resistance yet. However, it is convenient to use the Pitting Resistance Numerical Equivalent (PREN) to classify steel grades.
PREN =% Cr + 3.3 x% Mo + 16 x% N
Below is a table of the corrosion resistance of duplex steels compared to austenitic and ferritic grades.
Brand |
EN / UNS number |
Indicative PREN |
|
1.4016/
|
Ferritic |
||
1.4301/
|
Austenitic |
||
1.4509/
|
Ferritic |
||
1.4482/
|
Duplex |
||
1.4401/
|
Austenitic |
||
1.4521/
|
Ferritic |
||
316L 2.5 Mo |
Austenitic |
||
2101 LDX |
1.4162/
|
Duplex |
|
1.4362/
|
Duplex |
||
1.4062 / S32202 |
Duplex |
||
1.4539/
|
Austenitic |
||
1.4462/
|
Duplex |
||
Zeron 100 |
1.4501/
|
Duplex |
|
Ferrinox 255 / |
1.4507/
|
Duplex |
|
1.4410/
|
Duplex |
||
1.4547/
|
Austenitic |
It should be noted that this table can only serve as a guide when choosing a material. It is always necessary to consider how suitable a particular steel is for a particular corrosive environment.
Stress Corrosion Cracking (SCC)
SCC is one of the types of corrosion that occurs when there is a certain set of external factors:
- Tensile stress
- Corrosive environment
- Sufficiently high temperatures Usually 50 degrees Celsius, but in some cases, such as swimming pools, it can occur at temperatures around 25 degrees Celsius.
Unfortunately, common austenitic steels such as AISI 304 (analogs of DIN 1.4301 and 08X18H10) and AISI 316 (analogue of 10X17H13M2) are most susceptible to SCC. The following materials have much higher CR resistance:
- Ferritic stainless steels
- Duplex stainless steels
- Austenitic stainless steels with a high nickel content
The SCC resistance allows duplex steels to be used in many processes at high temperatures, in particular:
- In water heaters
- In the brewing tanks
- In desalination plants
Stainless steel pool frames are known for their SCC tendency. The use of conventional austenitic stainless steels in their manufacture, such as AISI 304 (analogue 08X18H10) and AISI 316 (analogue 10X17H13M2) is prohibited. Austenitic steels with a high nickel content, such as 6% Mo grades, are best suited for this purpose. However, in some cases, duplex steels such as AISI 2205 (DIN 1.4462) and super duplex steels can be considered as alternatives.
Factors hindering the proliferation of duplex steels
An attractive combination of high strength, wide range of corrosion resistance values, medium weldability, in theory, should carry great potential for increasing the share of duplex stainless steels in the market. However, it is important to understand what the disadvantages of duplex stainless steels are and why they are likely to remain niche players.
The advantage of high strength instantly turns into flaw, as soon as it comes to the manufacturability of material processing by pressure and machining. High strength also means lower plastic deformation than austenitic steels. Therefore, duplex steels are practically unsuitable for the production of products in which high ductility is required. And even when the ability to plastic deformation is at an acceptable level, still more force is required to give the required shape to the material, such as when bending pipes. There is one exception to the rule regarding poor machinability: LDX 2101 (EN 1.4162) from Outokumpu.
The smelting process for duplex stainless steels is much more complex than that of austenitic and ferritic steels. If the production technology is violated, in particular heat treatment, in addition to austenite and ferrite, a number of undesirable phases can form in duplex steels. The two most significant phases are depicted in the diagram below.
Click on the image to enlarge.
Both phases lead to the appearance of brittleness, that is, a loss of impact strength.
The formation of a sigma-phase (more than 1000 ° C) most often occurs when the cooling rate is insufficient during manufacturing or welding. The more alloying elements in the steel, the higher the likelihood of the formation of a sigma phase. Therefore, super duplex steels are most susceptible to this problem.
The 475 degree brittleness results from the formation of a phase called α ′ (alpha bar). Although the most dangerous temperature is 475 degrees Celsius, it can form at lower temperatures, up to 300 degrees C. This imposes restrictions on the maximum operating temperature of duplex steels. This limitation further narrows the range of possible applications.
On the other hand, there is a limitation on the minimum operating temperature of duplex steels, for which it is higher than that of austenitic steels. Unlike austenitic steels, duplex steels exhibit a brittle-ductile transition during impact testing. The standard test temperature for steels used in structures for offshore oil and gas production is minus 46 ° C. Duplex steels are generally not used at temperatures below minus 80 degrees Celsius.
A brief overview of the properties of duplex steels
- Design strength is twice that of austenitic and ferritic stainless steels
- Wide range of corrosion resistance values, allowing you to select the grade for a specific task
- Good impact resistance up to minus 80 ° С, limiting use in cryogenic environments.
- Exceptional resistance to stress corrosion cracking
- Good weldability of large cross-sections
- Greater difficulty in machining and stamping than austenitic steels
- The maximum operating temperature is limited to 300 degrees Celsius
Material taken from the British Stainless Steel Association website www.bssa.org.uk
Analogs of Russian and foreign steels
The countries and their applicable metal standards are listed below:
- Australia - AS (Australian Standard)
- Austria - ONORM
- Belgium - NBN
- Bulgaria - BDS
- Hungary - MSZ
- Great Britain - B.S. (British Standard)
- Germany - DIN (Deutsche Normen), WN
- European Union - EN (European Norm)
- Italy - UNI (Italian National Standards)
- Spain - UNE (Espaniol National Standards)
- Canada - CSA (Canadian Standards Association)
- China - GB
- Norway - NS (Standards Norway)
- Poland - PN (Poland Norm)
- Romania - STAS
- Russia - GOST (State standard) , THAT (Specifications)
- USA - AISI (American Iron and Steel Institute), ACI (American Concrete Institute), ANSI (American National Standards Institute), AMS (American Mathematical Society: Mathematics Research and Scholarship), API (American Petroleum Institute), ASME (American Society of Mechanical Engineers), ASTM (American Society of Testing and Materials), AWS (American Welding Society), SAE (Society of Automotive Engineers), UNS
- Finland - SFS (Finnish Standards Association)
- France - AFNOR NF (association francaise de normalization)
- Czech Republic - CSN (Czech State Norm)
- Sweden - SS (Swedish Standard)
- Switzerland - SNV (Schweizerische Normen-Vereinigung)
- Yugoslavia - JUS
- Japan - JIS (Japanese Industrial Standart)
- International standard - ISO (International Organization for Standardization)
In the United States, there are several systems of designation for metals and alloys associated with existing organizations on standardization. The most famous organizations are:
- AISI - American Iron and Steel Institute
- ACI - American Casting Institute
- ANSI - American National Standards Institute
- AMS - Aerospace Materials Specification
- ASME - American Society of Mechanical Engineers
- ASTM - American Society for Testing Materials
- AWS - American Welding Society
- SAE - Society of Engineers - Motorists
The following are the most popular steel designations used in the United States.
AISI notation system:
Carbon and alloy steels:
In the AISI designation system, carbon and alloy steels are generally identified with four numbers. The first two digits indicate the number of the steel group, and the last two - the average carbon content in steel multiplied by 100. So steel 1045
belongs to the group 10XX high-quality structural steels (non-sulfonated with a Mn content of less than 1%) and contains about 0.45% carbon.
Steel 4032
is doped (group 40XX), with an average content of C - 0.32% and Mo - 0.2 or 0.25% (the actual content of C in steel 4032
- 0.30 - 0.35%, Mo - 0.2 - 0.3%).
Steel 8625
is also doped (group 86XX) with an average content: C - 0.25% (real values 0.23 - 0.28%), Ni - 0.55% (0.40 - 0.70%), Cr - 0.50% (0.4 - 0.6%), Mo - 0.20% (0.15 - 0.25%) ...
In addition to four numbers, letters can also be found in the names of steels. Moreover, the letters B and L, meaning that the steel is alloyed with boron (0.0005 - 0.03%) or lead (0.15 - 0.35%), respectively, are placed between the second and third digits of its designation, for example: 51B60 or 15L48.
Letters M and E put in front of the name of steel, this means that the steel is intended for the production of irresponsible long products (letter M) or smelted in an electric furnace (letter E). The letter may be present at the end of the steel name H, meaning that the characteristic feature of this steel is hardenability.
Stainless steels:
AISI designations for standard stainless steels include three numbers followed by, in some cases, one, two or more letters. The first digit of the designation determines the steel grade. So the designations of austenitic stainless steels begin with numbers 2XX and 3XX, while ferritic and martensic steels are defined in the class 4XX... Moreover, the last two figures, unlike carbon and alloy steels, have nothing to do with chemical composition, but simply determine the serial number of the steel in the group.
Designations in carbon steels:
10XX - Non-sulfonated steels, Mn: less than 1%
11XX - Resulfinated steels
12XX - Re-phosphorized and resulfinated steels
15XX - Non-sulfonated steels, Mn: more than 1%
Alloy steel designations:
13XX - Mn: 1.75%
40XX - Mo: 0.2, 0.25% or Mo: 0.25% and S: 0.042%
41XX - Cr: 0.5, 0.8 or 0.95% and Mo: 0.12, 0.20 or 0.30%
43XX - Ni: 1.83%, Cr: 0.50 - 0.80%, Mo: 0.25%
46XX - Ni: 0.85 or 1.83% and Mo: 0.2 or 0.25%
47XX - Ni: 1.05%, Cr: 0.45% and Mo: 0.2 or 0.35%
48XX - Ni: 3.5% and Mo: 0.25%
51XX - Cr: 0.8, 0.88, 0.93, 0.95 or 1.0%
51XXX - Cr: 1.03%
52XXX - Cr: 1.45%
61XX - Cr: 0.6 or 0.95% and V: 0.13% min or 0.15% min
86XX - Ni: 0.55%, Cr: 0.50% and Mo: 0.20%
87XX - Ni: 0.55%, Cr: 0.50% and Mo: 0.25%
88XX - Ni: 0.55%, Cr: 0.50% and Mo: 0.35%
92XX - Si: 2.0% or Si: 1.40% and Cr: 0.70%
50BXX - Cr: 0.28 or 0.50%
51BXX - Cr: 0.80%
81BXX - Ni: 0.30%, Cr: 0.45% and Mo: 0.12%
94BXX - Ni: 0.45%, Cr: 0.40% and Mo: 0.12%
Additional letters and numbers following the numbers used to designate stainless steels according to AISI means:
xxxL - Low carbon content< 0.03%
xxxS - Normal carbon content< 0.08%
xxxN - Added nitrogen
xxxLN - Low carbon content< 0.03% + добавлен азот
xxxF - Increased content of sulfur and phosphorus
xxxSe - Added selenium
xxxB - Added silicon
xxxH - Extended carbon range
xxxCu - Added copper
Examples:
Steel 304
belongs to the austenitic class, the carbon content in it< 0.08%. В то же время в стали 304 L carbon total< 0.03%, а в стали 304 H carbon is defined in the range 0.04 - 0.10%. The specified steel, in addition, can be alloyed with nitrogen (then its name will be 304 N) or copper ( 304 Cu).
In steel 410
, belonging to the martensitic - ferritic class, the carbon content<< 0.15%, а в стали 410 S- carbon< 0.08%. В стали 430 F unlike steel 430
increased content of sulfur and phosphorus, and in steel 430 F Se added selenium as well.
ASTM designation system:
The designation of steels in the ASTM system includes:
- letter A, meaning that we are talking about black metal;
- serial number of the ASTM normative document (standard);
- the actual designation of the steel grade.
Usually, the American system of notation for physical quantities is adopted in ASTM standards. In the same case, if the standard provides a metric notation system, after its number, the letter M... ASTM standards, as a rule, determine not only the chemical composition of steel, but also a complete list of requirements for metal products. To designate the actual steel grades and determine their chemical composition, both the own ASTM designation system can be used (in this case, the chemical composition of steels and their marking is determined directly in the standard), and other designation systems, for example AISI - for bars, wire, billets, etc. others, or ACI - for stainless steel castings.
Examples:
A 516 / A 516M - 90 Grade 70 Here A defines that it is a black metal; 516
is the serial number of the ASTM standard ( 516M- this is the same standard, but in the metric notation system); 90
- year of publication of the standard; Grade 70- steel grade. In this case, we use our own ASTM steel designation system, here 70
determines the minimum tensile strength of steel during tensile tests (in ksi, which is about 485 MPa).
A 276 Type 304 L... This standard uses the designation of the steel grade in the AISI system - 304 L.
A 351 Grade CF8M... The ACI notation is used here: first letter C means that the steel belongs to the group of corrosion-resistant, 8
- determines the average carbon content in it (0.08%), M- means that molybdenum has been added to the steel.
A 335 / A 335M grade P22; A 213 / A 213M grade T22; A 336 / A 336M class F22... These examples use proprietary ASTM steels. The first letters mean that the steel is intended for the production of pipes ( P or T) or forgings ( F).
A 269 grade TP304... A combined notation system is used here. Letters TP determine that the steel is intended for the production of pipes, 304
is the designation for steel in the AISI system.
Universal notation system UNS:
UNS is a universal designation system for metals and alloys. It was created in 1975 with the aim of unifying the various designation systems used in the United States. According to UNS, steel designations consist of a letter identifying a group of steels and five numbers.
The UNS system is the easiest to classify AISI steels. For structural and alloy steels belonging to the group G, the first four digits of the name are the designation of the steel in the AISI system, the last digit replaces the letters that occur in the AISI designations. So letters B and L, meaning that the steel is alloyed with boron or lead, correspond to the numbers 1
and 4
, and the letter E, meaning that the steel is smelted in an electric furnace, - the number 6
.
AISI stainless steels start with the letter S and include the AISI steel designation (first three digits) and two additional numbers corresponding to the additional letters in the AISI designation.
Steel designations in the UNS system:
Dxxxxx - Steels with prescribed mechanical properties
Gxxxxx - AISI carbon and alloy steels (excluding tool steels)
Hxxxxx - The same, but for hardenable steels
Jxxxxx - Cast steel
Kxxxxx - Steels not included in the AISI system
Sxxxxx - Heat and corrosion resistant stainless steels
Txxxxx - Tool steels
Wxxxxx - Consumables
Additional letters and numbers following the numbers used to designate stainless steels according to UNS mean:
xxx01 - Low carbon content< 0.03%
xxx08 - Normal carbon content< 0.08%
xxx09 - Extended range of carbon content
xxx15 - Added silicon
xxx20 - Increased content of sulfur and phosphorus
xxx23 - Added selenium
xxx30 - Added copper
xxx51 - Added nitrogen
xxx53 - Low carbon content< 0.03% + добавлен азот
Examples:
Carbon steel 1045
has a designation in the system UNS G 10450, and alloy steel 4032
- G 40320.
Steel 51B60 doped with boron is called in the system UNS G 51601 and steel 15L48 alloyed with lead - G 15484.
Stainless steels are designated: 304
- S 30400, 304 L - S 30401, 304 H - S 30409, but 304 Cu - S 30430.
steel grade |
Analogues in US standards |
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CIS countries GOST |
Euronorms |
||
P0 M2 SF10-MP |
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P2 M10 K8-MP |
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R6 M5 K5-MP |
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R6 M5 F3-MP |
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R6 M5 F4-MP |
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R6 M5 F3 K8-MP |
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R10 M4 F3 K10-MP |
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R6 M5 F3 K9-MP |
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R12 M6 F5-MP |
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R12 F4 K5-MP |
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R12 F5 K5-MP |
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Structural steel:
steel grade |
Analogues in US standards |
||
CIS countries GOST |
Euronorms |
||
Basic assortment of stainless steel grades:
CIS (GOST) |
Euronorms (EN) |
Germany (DIN) |
USA (AISI) |
03 X17 H13 M2 |
X2 CrNiMo 17-12-2 |
||
03 X17 N14 M3 |
X2 CrNiMo 18-4-3 |
||
03 X18 N10 T-U |
|||
06 ХН28 МДТ |
X3 NiCrCuMoTi 27-23 |
||
08 X17 H13 M2 |
X5CrNiMo 17-13-3 |
||
08 X17 N13 M2 T |
X6 CrNiMoTi 17-12-2 |
||
X6 CrNiTi 18-10 |
|||
20 X25 N20 C2 |
X56 CrNiSi 25-20 |
||
03 X19 H13 M3 |
|||
02 X18 M2 BT |
|||
02 X28 N30 MDB |
X1 NiCrMoCu 31-27-4 |
||
03 X17 N13 AM3 |
X2 CrNiMoN 17-13-3 |
||
03 X22 H5 AM2 |
X2 CrNiMoN 22-5-3 |
||
03 X24 N13 G2 S |
|||
08 X16 N13 M2 B |
X1 CrNiMoNb 17-12-2 |
||
08 X18 N14 M2 B |
1.4583 X10 CrNiMoNb |
X10 CrNiMoNb 18-12 |
|
X8 СrNiAlTi 20-20 |
|||
X3 CrnImOn 27-5-2 |
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X6 CrNiMoNb 17-12-2 |
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X12 CrMnNiN 18-9-5 |
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Bearing steel:
steel grade |
Analogues in US standards |
||
CIS countries GOST |
Euronorms |
||
Spring steel:
steel grade |
Analogues in US standards |
||
CIS countries GOST |
Euronorms |
||
Heat resistant steel:
steel grade |
Analogues in US standards |
||
CIS countries GOST |
Euronorms |
||
Correspondence between domestic and foreign standards for steel and pipes
Steel standards
Germany |
European Union |
ISO-standard |
England |
France |
Italy |
Russia |
|
DIN 17200 |
heat-treated steel |
NFA 35-552 |
UNI 7845 |
GOST 4543-71 |
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case-hardened steel |
GOST 4543-71 |
||||||
hot rolled steel for annealed springs |
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spring wire and steel tape of rustless steel |
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ball bearing / trolley steel |
|||||||
temperature and high temperature material grade for screws and nuts |
GOST 5632-72 |
||||||
forging and rolled or forged steel bar of temperature, weldable steel |
ISO 2604/1 |
||||||
tool steel including high-speed steel |
GOST 1435 |
||||||
DIN 17440 |
BS 970/1 |
UNI 6900 |
GOST 5632-72 |
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rustless steel for medical equipment |
|||||||
rustless steel for surgical implant |
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valve material grade |
GOST 5632-72 |
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non-magnetic steel |
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SEW 470 |
heat-resistant steel |
BS 1554-81 |
UNI 6900 |
GOST 5632-72 |
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constructional steel |
1.4301 is the standard for austenitic stainless steels due to its good corrosion resistance, ease of shaping and workmanship, combined with its aesthetic appearance in polished, ground and ground conditions.
Standard |
EN 10028-7 - Flat-rolled steel for work under pressure. Part 7: Stainless steels EN 10088-1 - Stainless steels. Part 1: List of stainless steels EN 10088-2 - Stainless steels. Part 2: technical delivery conditions for general purpose corrosion-resistant steel sheets and strips 10088-3 - Stainless steels. Part 3. Technical delivery conditions for semi-finished products, rods, wire rod, drawn wire, profiles and products with improved surface finish made of corrosion-resistant steels for general use; EN 10088-4 - Stainless steel - Part 4: Technical delivery conditions for sheet plate and / or strip of corrosion-resistant steels for construction purposes EN 10088-5 - Stainless steels. Part 5. Technical delivery conditions for bars, wire rod, drawn wire, profiles and products with improved surface finish made of corrosion-resistant steels for construction EN 10151 - Stainless steel strips for springs - Technical delivery conditions EN 10216-5 - Seamless steel pipes for pressure purposes. Technical delivery conditions. Part 5. Stainless steel pipes EN 10217-7 - Welded steel pipes for pressure purposes. Technical delivery conditions. Part 7. Stainless steel tubes EN 10222-5 - Steel forgings for pressure vessels. Part 5. Martensitic, austenitic and austenitic-ferritic stainless steels EN 10250-4 - Open-die forging steel blanks for general use. Part 4. Stainless steels EN 10263-5 - Steel bars, strips and wires for cold heading and cold extrusion. Part 5. Basic delivery conditions for stainless steel EN 10264-4 - Steel wire and wire products. Part 4. Stainless steel wire EN 10269 - Steels and nickel alloys for fasteners used at high and / or low temperatures EN 10270-3 - Specification for steel wire for mechanical springs. Part 3. Stainless steel wire EN 10272 - Stainless steel rods for pressure service EN 10296-2 - Welded round steel pipes for mechanical and general technical use. Technical delivery conditions. Part 2. Stainless steels EN 10297-2 - Seamless round steel pipes for mechanical engineering and general technical purposes. Technical delivery conditions. Part 2. Stainless steels EN 10312 - Stainless welded pipes for the supply of aqueous liquids, including drinking water. Technical delivery conditions |
||
Rental | Pipe, rod, bar, wire rod, profile | ||
Other names | International (UNS) | S30400 | |
Commercial | Acidur 4567 |
Since 1.4301 is not resistant to intergranular corrosion in the welded state, 1.4307 should be mentioned if welding of large sections is required and no post-weld solution annealing treatment can be performed. Surface condition plays an important role in corrosion resistance. These steels, with polished surfaces, have a much higher corrosion resistance compared to coarser surfaces on the same material.
Chemical composition in% of steel X5CrNi18-10
The specific S value is determined depending on the required properties:
- for machining S 0.15 - 0.30
- for weldability S 0.008 - 0.030
- for polishing S< 0,015
Mechanical properties for grade X5CrNi18-10 (X5CrNi18-10)
EN 10028-7, EN 10088-2, EN 10088-4, EN 10312 | ||||||
Assortment | Thickness, mm, max | Yield strength, R 0,2 , MPa, min | Yield strength, R 1,0 , MPa, min | m , MPa | Oelongation,%, min (longitudinal and transverse specimens) at thickness | |
< 3 мм |
≥ 3 mm |
|||||
Cold rolled strip | 8 | 230 | 260 | 540 - 750 | 45 | 45 |
Hot rolled sheet | 13,5 | 210 | 250 | 520 - 720 | 45 | 45 |
Hot rolled strip | 75 | 210 | 250 | 520 - 720 | 45 | 45 |
EN 10250-4, EN 10272 (thickness ≤400) |
||||||
Thickness, mm | Yield strength, R 0,2 , MPa, min | Yield strength, R 1,0 , MPa, min | m , MPa | Elongation,%, (transverse samples), min | Work of impact energy KV 2, J, min | |
Longitudinal samples | Transverse samples | |||||
≤250 |
225 |
500 - 700 |
35 | 100 | 60 |
Solid solution treatment:
- temperature 1000 - 1100 ° C
- cooling: water or air
Heat treatment:
+ A - softening annealing
+ AT - treatment for solid solution
Surface quality:
+ C - cold deformation
+ LC - smooth rolling
+ PE - after stripping
EN 10264-4 | |
Diameter (d), mm | Ultimate tensile strength, MPa, min (NT) |
d ≤ 0.20 | 2050 |
0,20 < d ≤ 0,30 | 2000 |
0,30 < d ≤ 0,40 | 1950 |
0,40 < d ≤ 0,50 | 1900 |
0,50 < d ≤ 0,65 | 1850 |
0,65 < d ≤ 0,80 | 1800 |
0,80 < d ≤ 1,00 | 1750 |
1,00 < d ≤ 1,25 | 1700 |
1,25 < d ≤ 1,50 | 1650 |
1,50 < d ≤ 1,75 | 1600 |
1,75 < d ≤ 2,00 | 1550 |
2,00 < d ≤ 2,50 | 1500 |
2,50 < d ≤ 3,00 | 1450 |
EN 10270-3 |
||
Diameter (d), mm |
Ultimate tensile strength, MPa, max |
|
NS | Hs | |
d ≤ 0.20 | 2000 | 2150 |
0,20 < d ≤ 0,30 | 1975 | 2050 |
0,30 < d ≤ 0,40 | 1925 | 2050 |
0,40 < d ≤ 0,50 | 1900 | 1950 |
0,50 < d ≤ 0,65 | 1850 | 1950 |
0,65 < d ≤ 0,80 | 1800 | 1850 |
0,80 < d ≤ 1,00 | 1775 | 1850 |
1,00 < d ≤ 1,25 | 1725 | 1750 |
1,25 < d ≤ 1,50 | 1675 | 1750 |
1,50 < d ≤ 1,75 | 1625 | 1650 |
1,75 < d ≤ 2,00 | 1575 | 1650 |
2,00 < d ≤ 2,50 | 1525 | 1550 |
2,50 < d ≤ 3,00 | 1475 | 1550 |
3,00 < d ≤ 3,50 | 1425 | 1450 |
3,50 < d ≤ 4,25 | 1400 | 1450 |
4,25 < d ≤ 5,00 | 1350 | 1350 |
5,00 < d ≤ 6,00 | 1300 | 1350 |
6,00 < d ≤ 7,00 | 1250 | 1300 |
7,00 < d ≤ 8,50 | 1200 | 1300 |
8,50 < d ≤ 10,00 | 1175 | 1250 |
EN 10088-3 (1C, 1E, 1D, 1X, 1G and 2D), EN 10088-5 (1C, 1E, 1D, 1X, 1G and 2D) |
||||||
Thickness, mm |
Hardness HBW, max | Yield strength, R 0,2 , MPa, min | Yield strength, R 1,0 , MPa, min | Ultimate tensile strength R m , MPa | ||
Longitudinal samples | Transverse samples | |||||
≤160 |
215 | 190 | 225 | 500 - 700 | 45 | - |
> 160≤ 250 (EN 10088-3, EN 10088-5) > 160 ≤400 (EN 10272) |
215 | 190 | 225 | 500 - 700 | - | 35 |
Hot deformation: temperature 1200 - 900 ° C, air cooling
Solution treatment: temperature 1000 - 1100 ° C, cooling in water, in air
EN 10088-3 (2H, 2B, 2G and 2P), EN 10088-5 (2H, 2B, 2G and 2P) | ||||||
Thickness, mm (t) |
Yield strength, R 0,2
, MPa, min |
Ultimate tensile strength R m, MPa |
Elongation,%, min |
Impact work KV 2, J, min | ||
Longitudinal samples | Transverse samples | Longitudinal samples | Transverse samples | |||
≤ 10 | 400 | 600 - 950 | 25 | - | - | - |
10 < t ≤ 16 | 400 | 600 - 950 | 25 | - | - | - |
16 < t ≤ 40 |
190 | 600 - 850 | 30 | - | 100 | - |
40 < t ≤ 63 |
190 | 580 - 850 | 30 | - | 100 | - |
63 < t ≤ 160 |
190 | 500 - 700 | 45 | - | 100 | - |
160 < t ≤ 250 |
190 | 500 - 700 | - | 35 | - | 60 |
Ultimate tensile strength of wire with a diameter of ≥ 0.05 mm under 2H conditions
EN 10088-3 | ||||||||||
Ultimate tensile strength, MPa | ||||||||||
+ C500 |
+ C600 |
+ C700 |
+ C800 |
+ C900 |
+ C1000 |
+ C1100 |
+ C1200 |
+ C1400 | + C1600 | + C1800 |
500-700 |
600-800 |
700-900 |
800-1000 |
900-1100 |
1000-1250 |
1100-1350 |
1200-1450 |
1400-1700 |
1600-1900 |
1800-2100 |
Mechanical properties at room temperature of annealed wire in 2D state
EN 10088-3 (2D) | ||
Thickness, mm (t) |
Ultimate tensile strength R m , MPa |
Elongation,%, min |
0,05< t ≤0,10 | 1100 | 20 |
0,10< t ≤0,20 | 1050 | 20 |
0,20< t ≤0,50 |
1000 | 30 |
0,50< t ≤1,00 |
950 | 30 |
1,00< t ≤3,00 |
900 | 30 |
3,00< t ≤5,00 |
850 | 35 |
5,00< t ≤16,00 |
800 | 35 |
Mechanical properties for rods at room temperature of steels in the hardened (2H) state
Heat treatment before subsequent deformation
- Treatment for solid solution: 1020 - 1100 ° C
- Quenching in water, air or gas (cooling must be fast enough)
Hot deformation before post-processing
- temperature 1100 - 850 ° С
- cooling in air or in a gas environment
Elevated temperature tests
Temperature, ° C |
EN 10269 (+ AT) | EN 10088-3, EN 10088-5, EN 10216-5, EN 10272 |
|||
Yield strength, min, R p0.2 , MPa |
|
Yield strength, min, R p0.2 , MPa |
Yield strength, min, R p0.2 , MPa |
Ultimate tensile strength, min, Rm, MPa (EN 10272) |
|
50 | 177 | 480 | 180 (EN 10216-5) | 218 (EN 10216-5) | - |
100 | 155 | 450 | 155 | 190 | 450 |
150 | 140 | 420 | 140 | 170 | 420 |
200 | 127 | 400 | 127 | 155 | 400 |
250 | 118 | 390; | 118 | 145 | 390 |
300 | 110 | 380 | 110 | 135 | 380 |
350 | 104 | 380 | 104 | 129 | 380 |
400 | 98 | 380 | 98 | 125 | 380 |
450 | 95 | 375 | 95 | 122 | 370 |
500 | 92 | 260 | 92 | 120 | 360 |
550 | 90 | 335 | 90 | 120 | 330 |
600 | - | 300 | - | - | - |
Temperature, ° C |
EN 10088-2, EN 10088-4, EN 10028-7, EN 10217-7, EN 10222-5, EN 10312 | |
Yield strength, min, R p0.2 , MPa |
Yield strength, min., R p1,0, min, MPa |
|
50 | 190 (EN 10028-7), 180 (EN 10217-7) |
228 (EN 10028-7), 218 (EN 10217-7) |
100 | 157 | 191 |
150 | 142 | 172 |
200 | 127 | 157 |
250 | 118 | 145 |
300 | 110 | 135 |
350 | 104 | 129 |
400 | 98 | 125 |
450 | 95 | 122 |
500 | 92 | 120 |
550 | 90 | 120 |
Physical properties
Density of steel (weight) X5CrNi18-10- 7.9 g / cm 3
Technological properties
Weldability | ||
According to ISO / TR 20172 | Group 8.1 |
The closest equivalents (analogs) of steel X5CrNi18-10
Corrosion resistant
Due to the moderate carbon content of 1.4301, this grade of stainless steel is susceptible to sensitization. The formation of chromium carbides and associated chromium-plated regions that form around these deposits makes this class of steel susceptible to intergranular corrosion. Although there is no danger of intergranular corrosion in the state (solution annealed), intergranular corrosion may occur after welding or high temperature processing. 1.4301 is resistant to corrosion in most environments with low chloride and salt concentrations. 1.4301 is not recommended for applications where it comes in contact with seawater and is not recommended for use in swimming pools.
Welding
1.4301 can be welded with or without filler. If the use of filler is required, it is recommended to use Novonit 4316 (AISI 308L). Maximum spacing temperature 200 ° C. Post-weld heat treatment is not required.Forging
1.4301 is typically heated between 1150 ° C and 1180 ° C to allow forging between 1180 ° C and 950 ° C. Forging is followed by air cooling or water quenching when there is no danger of distortion.Treatment
The following cutting parameters are suggested as a guideline when machining the NIRO-CUT 4301 using hard metal cutting tools.